
Hazardous Materials Firefighter Course
This Hazardous Materials Firefighter Course gives you the tactical knowledge and hands-on procedures to respond safely to chemical, biological, and radiological incidents. From scene size-up and PPE selection to decontamination and patient triage, every module is built around real operational decisions. Train to the standards that protect your crew, your community, and your career.
What you will learn:
You will learn to classify hazardous materials using DOT systems, read shipping papers, and apply the Emergency Response Guidebook under pressure. You will select and don the correct PPE level for each entry condition and operate detection instruments to make data-driven decisions. The course covers incident command structure, control zone establishment, and multi-agency coordination. You will execute liquid spill containment, gas control, and product transfer operations using proven field techniques. Decontamination corridor setup, triage of contaminated patients, and antidote administration protocols are also covered in full. Advanced modules address transportation incidents, fixed-facility releases, and CBRN threat recognition.
How you study in practice Hazardous Materials Firefighter Course
How you practise Hazardous Materials Firefighter Course
For companies looking to train their teams
With Dedika for Businesses, the course includes exercises and examples tailored to your own business and the specific needs of your company.
Course content
8 Chapters • 40 LessonsDuration between 4 and 360 hours (you decide)
Chapter 1HideHide detailsSee detailsFoundations of Hazardous Materials Response
Foundations of Hazardous Materials Response
Lesson 1 • Properties of Hazardous Materials
Introduces physical and chemical properties that drive hazard behaviour. Students connect property data to real-world exposure and ignition risks.
Lesson 2 • Regulatory Framework and Responder Roles
Examines occupational safety standards, hazmat training levels, and incident command roles. Clarifies legal duties and competency expectations for each responder tier.
Lesson 3 • Initial Scene Size-Up Procedures
Develops systematic approach to evaluating a hazmat scene before committing resources. Proper size-up prevents premature entry and guides zone establishment.
Lesson 4 • Hazardous Materials Classification Systems
Covers the nine DOT hazard classes, UN numbering, and placard systems. Establishes the classification vocabulary used throughout all subsequent response decisions.
Lesson 5 • Recognition and Identification Tools
Teaches use of the Emergency Response Guidebook, safety data sheets, and shipping papers. Accurate identification is the gateway to all protective action decisions.
Chapter 2HideHide detailsSee detailsPersonal Protective Equipment for Hazmat
Personal Protective Equipment for Hazmat
Lesson 1 • Donning and Doffing Procedures
Teaches step-by-step donning and doffing sequences with buddy-check protocols. Procedural discipline at this stage directly reduces contamination transfer risk.
Lesson 2 • PPE Inspection, Maintenance, and Limitations
Addresses pre-use inspection criteria, storage requirements, and service life tracking. Understanding PPE limitations prevents overconfidence during high-risk entries.
Lesson 3 • Chemical Protective Clothing Selection
Examines suit materials, permeation resistance ratings, and manufacturer compatibility charts. Correct material selection prevents chemical breakthrough during entry.
Lesson 4 • PPE Protection Levels Overview
Defines Levels A through D and the hazard conditions requiring each. Connects protection level selection to chemical property data from Chapter 1.
Lesson 5 • Self-Contained Breathing Apparatus
Covers SCBA components, air supply calculations, and emergency procedures. Proficient SCBA use is prerequisite to all entry operations covered later.
Chapter 3HideHide detailsSee detailsHazmat Incident Command and Scene Management
Hazmat Incident Command and Scene Management
Lesson 1 • Establishing Control Zones
Defines hot, warm, and cold zone boundaries and the criteria for setting each. Zone integrity is the primary mechanism for preventing responder contamination.
Lesson 2 • Evacuation and Shelter-in-Place Decisions
Teaches decision factors for evacuation versus shelter-in-place using dispersion modelling concepts. Correct protective action selection minimises civilian casualties.
Lesson 3 • Resource Coordination and Mutual Aid
Covers requesting specialised teams, equipment caches, and interagency communication protocols. Effective resource management sustains operations beyond initial responder capacity.
Lesson 4 • Incident Command System for Hazmat
Adapts standard ICS structure to hazmat-specific positions and functions. Builds on responder roles introduced in Chapter 1 within a command framework.
Lesson 5 • Scene Documentation and Reporting
Establishes requirements for incident logs, exposure records, and regulatory notifications. Accurate documentation supports post-incident review and legal compliance.
Chapter 4HideHide detailsSee detailsDetection, Monitoring, and Air Sampling
Detection, Monitoring, and Air Sampling
Lesson 1 • Instrument Selection and Calibration
Covers matching instruments to target chemicals and performing field calibration. Proper calibration is mandatory before any instrument reading can be trusted.
Lesson 2 • Interpreting Monitoring Data
Develops skills to compare readings against IDLH, LEL, and ERPG values. Data interpretation directly drives entry authorisation and PPE upgrade decisions.
Lesson 3 • Principles of Hazmat Detection
Explains detection technologies including photoionisation, electrochemical, and colorimetric methods. Understanding operating principles prevents misinterpretation of instrument readings.
Lesson 4 • Air Monitoring Survey Techniques
Teaches systematic survey patterns for perimeter, entry, and interior monitoring. Structured survey methods ensure no hazard zone is missed during assessment.
Lesson 5 • Continuous Monitoring During Operations
Addresses real-time monitoring protocols for entry teams and perimeter sentinels. Continuous data feeds allow immediate response to changing atmospheric conditions.
Chapter 5HideHide detailsSee detailsHazmat Containment and Control Operations
Hazmat Containment and Control Operations
Lesson 1 • Reactive and Unstable Material Handling
Addresses water-reactive, oxidizer, and polymerising material control tactics. These materials require deviation from standard containment approaches due to reaction risk.
Lesson 2 • Product Transfer Operations
Covers pump selection, transfer hose compatibility, and grounding procedures for flammable liquids. Safe transfer eliminates the source container as an ongoing hazard.
Lesson 3 • Liquid Spill Containment
Teaches diking, damming, diverting, and retention methods for liquid hazmat releases. Containment prevents migration to drains, waterways, and uncontrolled areas.
Lesson 4 • Gas and Vapour Control Methods
Addresses vapour suppression, dilution, and dispersion tactics for gaseous releases. Gas control decisions depend on flammability and toxicity data from Chapter 1.
Lesson 5 • Leak Isolation Techniques
Covers valve shutoff, plugging, patching, and overpacking methods for containers under pressure. Isolation stops the release and reduces the scope of subsequent operations.
Chapter 6HideHide detailsSee detailsDecontamination Procedures and Operations
Decontamination Procedures and Operations
Lesson 1 • Decon Effectiveness Verification
Covers swipe sampling, instrument verification, and medical surveillance after decon. Verification confirms that personnel are safe to transition to the cold zone.
Lesson 2 • Decontamination Principles and Theory
Explains dilution, absorption, neutralisation, and disinfection as decon mechanisms. Mechanism selection depends on the chemical properties established in earlier chapters.
Lesson 3 • Technical Decontamination Procedures
Teaches the full multi-station decon line for entry team personnel and equipment. Technical decon follows emergency decon and ensures thorough contamination removal.
Lesson 4 • Emergency Decontamination Setup
Covers rapid decon corridor establishment for ambulatory and non-ambulatory victims. Speed of setup directly affects victim outcome in mass-casualty hazmat events.
Lesson 5 • Decontamination Solution Selection
Addresses solution compatibility with specific chemical families and skin-safe formulations. Incorrect solution selection can worsen contamination or cause secondary injury.
Chapter 7HideHide detailsSee detailsHazmat Medical Management and Triage
Hazmat Medical Management and Triage
Lesson 1 • Patient Packaging and Hospital Handoff
Addresses contamination-controlled packaging, transport protocols, and receiving facility notification. Proper handoff prevents secondary contamination of hospital staff.
Lesson 2 • Symptom Recognition by Chemical Class
Teaches clinical signs associated with nerve agents, corrosives, asphyxiants, and irritants. Symptom pattern recognition enables rapid treatment before lab confirmation.
Lesson 3 • Toxicology Fundamentals for Responders
Covers routes of exposure, dose-response relationships, and target organ effects. Toxicological understanding drives triage priority and treatment selection.
Lesson 4 • Antidote and Supportive Treatment
Covers atropine, pralidoxime, cyanide antidote kits, and oxygen therapy protocols. Antidote administration timing is critical to patient survival in toxic exposures.
Lesson 5 • Hazmat Patient Triage Methods
Applies START and SALT triage systems to contaminated patient populations. Triage must occur before decon to prioritise life-threatening cases appropriately.
Chapter 8HideHide detailsSee detailsAdvanced Hazmat Scenarios and Tactical Integration
Advanced Hazmat Scenarios and Tactical Integration
Lesson 1 • Transportation Incident Response
Applies classification, PPE, monitoring, and containment skills to highway, rail, and pipeline incidents. Transportation scenarios introduce multi-container and multi-product complexity.
Lesson 2 • Weapons of Mass Destruction Awareness
Introduces CBRN threat recognition, scene indicators, and modified response protocols. WMD incidents require immediate escalation beyond standard hazmat response procedures.
Lesson 3 • Integrated Tabletop Scenario Exercises
Facilitates command-level decision-making through structured tabletop scenarios. Tabletop exercises expose gaps in planning before live field exercises are conducted.
Lesson 4 • Fixed-Facility Release Operations
Covers pre-incident planning use, process knowledge, and facility liaison coordination. Fixed-facility incidents offer pre-plan data that must be integrated into tactical decisions.
Lesson 5 • Live Field Practical Exercises
Executes full-scale field exercises integrating PPE, monitoring, containment, decon, and medical. Performance is evaluated against measurable competency benchmarks.
Your valid completion certificate
This course is for you:
Structural firefighter: ready to add certified hazmat technician skills to their role.
Industrial emergency response team member: needs formal training to match job demands.
EMS professional: wants to manage contaminated patients safely at chemical incidents.
Career-change candidate: transitioning from military CBRN roles into civilian fire service.
Fire officer: building the technical foundation required for hazmat team leadership.
Safety coordinator: responsible for facility emergency planning and responder preparedness.
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